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9:21 PM Defects of Voltaic Cell |
A simple voltaic cell has two major defects. They are
- Local action and
- Polarisation
- Local Action : This is caused by the impurities
present in zinc rod. When the zinc rod isimmersed in acid, the zinc
atoms and the impurity atoms form a large number of local cells and the
zinc rod gets consumed even when the cell is not in use. This defect can
be avoided by using amalgamated zinc rods. Mercury dissolves zinc and
allows only zinc atoms to come into contact with acid and thus avoids
formation of local cells.
- Polarisation: The hydrogen ions reaching the
negative electrode get accumulated preventing further neutralization of
hydrogen ions. This results in decrease of emf of the cell and produces a
back emf. This can be eliminated by :
(i) Mechanical method. In this method, the hydrogen layer
from the positive electrode is removed, using a brush. But this method
is not so satisfactory.
(ii) Electrochemical method. In this method, a liquid called
depolariser is used. The hydrogen ions react with this and some other
gas is produced which does not – cause polarisation.
(iii) Chemical method. In this method, hydrogen is converted to water
with an oxidising agent like manganese dioxide, potassium dichromate
etc.
courtesy : chemistry.2luv.in
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